To determine the amount of alcohol
in the beer they
are making, brewers compare the specific gravity of the beer
before it starts fermenting to its specific gravity when it is
finished fermenting.
The specific gravity is a measure of the density of a
liquid relative to water. The density of water is 1 kilogram
per liter, so if the specific gravity of a liquid is 1.06,
one liter of that liquid will weigh 1.06 kg.
A hydrometer used to
measure the specific gravity of liquids. Notice the
reading of 1.000 for water.
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The liquid that will form the beer is called a wort
(pronounced wert). Its specific gravity is always higher
than water because it contains a lot of dissolved sugars.
Yeast added to the wort will convert some of these dissolved
sugars into ethyl alcohol. When the beer is finished, the
specific gravity is always less than when it started,
because some of the sugars have been converted into alcohol,
which is less dense than water (0.79 kg/L).
Glucose (C6H12O6) is the main sugar that will be
converted to alcohol. Many reactions take place inside the
yeast that ultimately convert each glucose molecule into two
molecules of ethyl alcohol (CH3CH2OH) and two molecules of carbon
dioxide (CO2).
C6H12O6
=> 2(CH3CH2OH) + 2(CO2)
If you check the periodic table, you can figure out the
molecular weights of these two molecules. The molecular
weight of ethyl alcohol is 46.0688 and the molecular weight
of carbon dioxide is 44.0098. You will need these numbers to
calculate the alcohol content of the beer.
During the fermentation process most of the carbon dioxide
that forms from the reaction bubbles out of the solution and
leaves the fermentation vessel by way of a vent. You can say
that all of it leaves, because the amount the remains in the
beer is very small compared to the amount that leaves.
If you look at the equation for the reaction you see that
each glucose is split into two ethyl alcohol molecules and
two carbon dioxide molecules. That means for each carbon
dioxide molecule that leaves the fermentation vessel, one
ethyl alcohol molecule must be formed inside the vessel. If
you look back at the molecular weights you can say that for
each 44.0098 grams of CO2
that leaves the vessel 46.0688 grams of ethyl alcohol are
formed. Put another way, for each gram of CO2 that bubbles off, about 1.05 grams
of ethyl alcohol are produced.
You can compare the starting specific gravity to the final
specific gravity. If the starting gravity of the wort is
1.06, and after fermentation, the gravity is 1.02.
Subtracting the second from the first gives us the weight of
CO2 that left the vessel. That is
equal to 0.04 kg/L. Then you multiply by 1.05 to get the
weight of the alcohol in the container. That is 0.042 kg/L.
Now that you know both the mass of the solution (1.02 kg/L)
and the mass of the alcohol (0.042 kg/L) you can calculate
the percentage of alcohol by mass by dividing the two. This
gives 0.042 / 1.02, which equals 0.041, or 4.1 percent.
It is important to note that the percentage of alcohol by
mass is higher than the percentage of alcohol by volume
because an equal mass of alcohol occupies more volume than
water would. So to convert from percent alcohol by mass to
percent alcohol by volume you just divide by the density of
alcohol. In this case you get 4.1/0.79 or 5.2 percent
alcohol by volume.
In Colorado the beer sold in grocery stores has to be low
alcohol "3.2" beer. It can contain no more than 3.2 percent
alcohol by mass. But the beer sold in liquor stores is
labeled by volume, and most beer is about 5 percent alcohol
by volume. But when you convert from weight to volume you
find that the "3.2" beer is really 4 percent alcohol by
volume. Still a pretty big difference, but maybe not quite
as big as you might think.
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